OK, the dibond is being used as a substrate for a sign, that's it, the sign will be fixed to the door, inevitably this will strengthen the door, it just will! the question is what base coat is "recommended" before I use acrylic paint to sign letter.
My mistake, I do apologise I have since posted the first question on another forum and the answer is:
http://www.justpaint.org/painting-on-dibond/
The best bond was achieved using Sherwin Williams DTM Bonding Primer and XIM’s UMA ( Urethane Modified Acrylic ) Bonder Primer, followed by acrylic gesso. You could certainly put an oil ground on top of the bonder / primer if you prefer that rather than acrylic gesso. They did not test oils directly on the Dibond. I personally find the polyester surface coat to be far too thin, non porous and slippery to be confident of the bond strength painting directly on it.
I have had excellent adhesion using several brands of acrylic gesso alone, but have not used W&N. In the future I do plan to use the XIM UMA or the DTM followed by acrylic gesso or oil ground. Just trying to decide which one to buy. They run about $50 / gallon.