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The term "outgassing" implies that there is a gas inside the vinyl. There is not. There is a solvent that will evaporate if it is exposed to an environment that contains less solvent than the vinyl. When a liquid evaporates it changes from a liquid to a gas. The correct term should be...
"Outgassing" sounds more impressive than "the solvent evaporates". The solvents in the ink evaporate from the surface of the print. If you laminate the print before the solvents have fully evaporated, the solvents simply pass through the laminate the same way application fluid does.....through...
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