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"3M™ Scotchlite™ Reflective Material – Transfer Films are designed for use on safety garments and in athletic and casual wear.Part of the reflective elements of reflective vinyl is made from aluminum.
3M Scotchlight reflective for sure has/had an aluminum layer.
If anyone cares to read about it,
http://multimedia.3m.com/mws/mediawebserver?mwsId=SSSSSu7zK1fslxtUNYt9o8_Gev7qe17zHvTSevTSeSSSSSS--
The mold is the aluminum molecules corroding under the top clear sheet.
I had some of the "A" word stuff turn black some years ago. I looked at it under a microscope and it appeared to be corrosion.
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We're talking about vehicle graphics here, not clothing. Try to follow along.